Research Article | Volume: 8, Issue: 8, August, 2018

Application of Natural Deep Eutectic Solvent-Based Ultrasonic Assisted Extraction of Total Polyphenolic and Caffeine Content from Coffe Beans (Coffea Beans L.) For Instant Food Products

Islamudin Ahmad Adela Surya Pertiwi Yulietta Heryani Kembaren Arif Rahman Abdul Mun’im   

Open Access   

Published:  Aug 31, 2018

DOI: 10.7324/JAPS.2018.8819
Abstract

This study aims to determine and obtain the total polyphenolic and caffeine content from coffee beans (Coffea arabica L.) with some combination of factors. The extraction process was performed using natural deep eutectic solvent-based ultrasonic-assisted extraction (NADES-UAE) method with the different condition including extraction time, NADES ratio, and liquid-solid ratio. The total polyphenolic content was calculated using a microplate reader 96 well. The caffeine content was examined using high-performance liquid chromatography. Based on the results demonstrated the effect of different NADES components (namely lactic acid-sucrose and citric acid-glucose) on the total polyphenolic and caffeine content. The highest total polyphenolic content was 87.01 mg GAE/g sample (2 g/g lactic acid-sucrose ratio and 10 mL/g liquid-solid ratio for 15 minutes) and 62.91 mg GAE/g sample (5 g/g citric acid-glucose ratio and 15 mL/g liquid-solid ratio for 15 minutes). Whereas, the highest caffeine content was 4.45 mg/g (4 g/g lactic acid-sucrose and 15 mL/g liquid-solid ratio for 35 minutes) and 1.30 mg/g (2 g/g lactic acid-sucrose and 30 mL/g liquid-solid ratio for 5 minutes), respectively. These results were obtained from the green extraction method with rapid, easy, inexpensive, and environmentally friendly.


Keyword:     Caffeine content Coffea arabica L natural deep eutectic solvent total polyphenolic content ultrasonic-assisted extraction.


Citation:

Ahmad I, Pertiwi AS, Kembaren YH, Rahman A, Mun’im A. Application of Natural Deep Eutectic Solvent-Based Ultrasonic Assisted Extraction of Total Polyphenolic and Caffeine Content from Coffe Beans (Coffea Beans L.) For Instant Food Products. J App Pharm Sci, 2018; 8(08): 138-143.

Copyright: © The Author(s). This is an open-access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Reference

Ahmad I, Yanuar A, Mulia K, Mun'im A. Extraction of polyphenolic content from Peperomia pellucida (L) Kunth herb with 1-ethyl-3-methylimidazolium bromide as a green solvent. Indian Journal of Pharmaceutical Sciences, 2017a; 79:1013-1017. https://doi.org/10.4172/pharmaceutical-sciences.1000320

Ahmad I, Yanuar A, Mulia K, Mun'im, A. Optimization of ionic liquid-based microwave-assisted extraction of polyphenolic content from Peperomia pellucida (L) Kunth using response surface methodology. Asian Pacific Journal of Tropical Biomedicine, 2017b; 7:pp. 660-665. https://doi.org/10.1016/j.apjtb.2017.06.010

Ali MM, Eisa M, Taha MI, Zakaria BA, Elbashir AA. Determination of caffeine in some Sudanese beverages by high performance liquid chromatography. Pakistan Journal of Nutrition, 2012; 11:336-342. https://doi.org/10.3923/pjn.2012.336.342

Amorim ACL, Hovell AMC, Pinto AC, Eberlin MN, Arruda NP, Pereira EJ, Bizzo HR, Catharino RR, Filho ZBM., Rezende, C.M. Green and roasted Arabica coffees differentiated by ripeness, process and cup quality via electrospray ionization mass spectrometry fingerprinting. Journal of the Brazilian Chemical Society, 2009; 20:313-321. https://doi.org/10.1590/S0103-50532009000200017

Baeza G, Sarria B, Bravo L, Matheos R. Exhaustive qualitative LC-DAD-MS analysis of Arabica green coffee beans: cinnamoyl-glycosides and cinnamoylshikimic acids as new polyphenols in green coffee. Journal of Agricultural and Food Chemistry, 2016; 64:9663-9674. https://doi.org/10.1021/acs.jafc.6b04022

Belguidoum K, Amira-Guebailia H, Boulmokh Y, Houache, O. HPLC coupled to UV-vis detection for quantitative determination of phenolic compounds and caffeine in different brands of coffee in the Algerian market. Journal of the Taiwan Institute of Chemical Engineers, 2014; 45:1314-1320. https://doi.org/10.1016/j.jtice.2014.03.014

Blum J, Lemaire B, Lafay S. Effect of a green decaffeinated on glycaemia: a pilot prospective clinical study. Nutrafoods, 2007; 6:13-17.

Bobo-García G, Davidov-Pardo G, Arroqui C, Virseda P, Marin- Arroyo MR, Navarro M. Intra-laboratory validation of microplate methods for total phenolic content and antioxidant activity on polyphenolic extracts, and comparison with conventional spectrophotometric methods. Journal of the Science of Food and Agriculture, 2014; 95:204-209. https://doi.org/10.1002/jsfa.6706

Bubalo MC, Ćurko N, Tomašević M, Ganić KK, Redovnikovic IR. Green extraction of grape skin phenolics by using deep eutectic solvents. Food Chemistry, 2016; 200:159-166. https://doi.org/10.1016/j.foodchem.2016.01.040

Chemat F, Vian MA. 2014. Green Chemistry and Sustainable Technology: Alternative Solvents for Natural Products Extraction. Heildelberg, New York, Dordrecht, London, Springer, US.

Dai Y, van Spreonsen J, Witkamp GJ, Verpoorte R, Choi YH. Ionic liquids and deep eutectic solvents in natural products research: mixtures of solids as extraction solvents. Journal of Natural Products. 2013. https://doi.org/10.1021/np400051w

Dai Y, Witkamp GJ, Verpoorte R, Choi YH. Natural deep eutectic solvents as a new extraction media for phenolic metabolites in Carthamus tinctorius L. Analytical Chemistry, 2013; 85:6272-6278. https://doi.org/10.1021/ac400432p

Dai Y, Witkamp GJ, Verpoorte R, Choi YH. Tailoring properties of natural deep eutectic solvents with water to facilitate their applications. Food Chemistry, 2015; 187:14-19. https://doi.org/10.1016/j.foodchem.2015.03.123

Dai Y, Rozema E, Verpoorte R, Choi YH. Application of natural deep eutectic solvents to the extraction of anthocyanins from Catharanthus roseus with high extractability and stability replacing conventional organic solvents. Journal of Chromatography A, 2016; 1434:50-56. https://doi.org/10.1016/j.chroma.2016.01.037

Fernández MÁ, Espino M, Gomez FJV, Silva MF. Novel approaches mediated by tailor-made green solvents for the extraction of phenolic compounds from agro-food industrial by-products. Food Chemistry, 2017; 239:671-678. https://doi.org/10.1016/j.foodchem.2017.06.150

García A, Rodríguez-Juan E, Rodríguez-Gutiérrez G, Rios JJ, Fernández-Bola-os J. Extraction of phenolic compounds from virgin olive oil by deep eutectic solvents (DESs). Food Chemistry, 2016; 197:554-561. https://doi.org/10.1016/j.foodchem.2015.10.131

Hečimović I, BelšÄak-Cvitanović A, Horžić D, Komes D. Comparative study of polyphenols and caffeine in different coffee varieties affected by the degree of roasting. Food Chemistry, 2011; 129:991-1000. https://doi.org/10.1016/j.foodchem.2011.05.059

Kerton FM. Alternative Solvents for Green Chemistry. Cambridge: The Royal Society of Chemistry (RSC) Publishing. 2009.

Kozuma K, Tsuchiya S, Kohori J, Hase T, Tokimitsu I. Antihypertensive effect of green coffee bean extract on mildly hypertensive subjects. Hypertension research, 2005; 28:711-718. https://doi.org/10.1291/hypres.28.711

Lu W, Alam MA, Pan Y, Wu J, Wang Z, Yuan Z. A new approach of microalgal biomass pretreatment using deep eutectic solvents for enhanced lipid recovery for biodiesel production. Bioresource Technology, 2016; 218:123-128. https://doi.org/10.1016/j.biortech.2016.05.120

Njoroge,JM, Agwanda CO, Kingori PN, Karanja AM, Gathaara MPH. Coffee. in Chopra VL, Peter KV. (Eds) Handbook of Industrial Crops. New York, USA: Haworth Press, pp. 295-333. 2005.

Pan M, Zhao G, Ding C, Wu B, Lian Z, Lian H. Physicochemical transformation of rice straw after pretreatment with a deep eutectic solvent of choline chloride/urea. Carbohydrate Polymers, 2017; 176:307-314. https://doi.org/10.1016/j.carbpol.2017.08.088

Pham HNT, Nguyen VT, Vuong QV, Bowyer MC, Scarlett CJ. Bioactive compound yield and antioxidant capacity of Helicteres hirsuta Lour. stem as affected by various solvents and drying methods. Journal of Food Processing and Preservation, 2017; 41:1-9. https://doi.org/10.1111/jfpp.12879

Rahardjo P. Panduan Budi Daya dan Pengelolaan Kopi Arabika dan Robusta. Jakarta: Penerbar Swadaya. 2012.

Wang H, Ma X, Cheng Q, Xi X, Zhang L. Deep eutectic solvent-based microwave-assisted extraction of baicalin from Scutellaria baicalensis Georgi. Journal of Chemistry, 2018; 2018:1-10. https://doi.org/10.1155/2018/9579872

Watanabe T, Arai Y, Kusaura T, Okawa W, Kajihara Y, Saito I. The blood pressure-lowering effect and safety of chlorogenic acid from green coffee bean extract in essential hypertension. Journal of Clinical and Experimental Hypertension, 2006; 28:439-449. https://doi.org/10.1080/10641960600798655

Wei Z, Qi X, Li T, Luo M, Wang W, Zu Y, Fu Y. Application of natural deep eutectic solvents for extraction and determination of phenolics in Cajanus cajan leaves by ultra performance liquid chromatography. Separation and Purification Technology, 2015; 149:237-244. https://doi.org/10.1016/j.seppur.2015.05.015

Wei ZF, Wang XQ, Peng X, Wang W, Zhao CJ. Fast and green extraction and separation of main bioactive flavonoids from Radix Scutellariae. Industrial Crops and Products, 2015; 63:175-181. https://doi.org/10.1016/j.indcrop.2014.10.013

Xia B, Yan D, Bai Y, Xie J, Cao Y, Liao D, Lin L. Determination of phenolic acids in Prunella vulgaris L.: a safe and green extraction method using alcohol-based deep eutectic solvents. Analytical Methods, 2015; 7:9354-9364. https://doi.org/10.1039/C5AY02035B

Xu H, Wang W, Liu X, Yuan F, Gao Y. Antioxidative phenolics obtained from spent coffee grounds (Coffea arabica L.) by subcritical water extraction. Industrial Crops and Products, 2015; 76:946-954. https://doi.org/10.1016/j.indcrop.2015.07.054

Zhang X, Li W, Chen W, Kelly DP, Wang X, Zheng K, Du Y. Improvement of near infrared spectroscopic (NIRS) analysis of caffeine in roasted arabica coffee by variable selection method of stability competitive adaptive reweighted sampling (SCARS). Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2013; 114:350-356. https://doi.org/10.1016/j.saa.2013.05.053

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